The diffusion and trapping of hydrogen in high purity

Visualization of hydrogen depth profile by means of

Dec 30,2009 The diffusion and trapping of hydrogen in high purity#0183;An apparent hydrogen diffusion coefficient is determined from the latter to be ,which agrees well with the extrapolation of Frauenfelder's data obtained at elevated temperatures.The near-surface localized one is attributed to hydrogen trapping with a trapping energy of 0.84 The diffusion and trapping of hydrogen in high purity#177;0.04 eV. of high purity (99.99%) W made by powder metallurgy.The diffusion and trapping of hydrogen in high purity Nov 01,1998 The diffusion and trapping of hydrogen in high purity#0183;The diffusion and trapping of hydrogen in high purity (99.999 wt%),polycrystalline aluminum was investigated using both isothermal and constant heating rate desorption techniques.Constant heating rate desorption was used to elucidate the effects of microstructural trap states on the apparent diffusivity of hydrogen in aluminum.The Production of Ultra-pure Hydrogen Johnson Matthey The successful development of Johnson Matthey Metals palladium alloy diffusion units for the production of ultra-high purity hydrogen is largely dependent on comprehensive testing of all units before they are released to customers.This article describes the test procedures and the equipment used in testing.

The Application of a Diffusion/Trapping Model for Hydrogen

The Application of a Diffusion/Trapping Model for Hydrogen Ingress in High-Strength Alloys B.G.Pound 1 Materials Research Laboratory,SRI International,Menlo Park,California 94025.Technical Reference on Hydrogen Compatibility of8.GA Young and JR Scully.The diffusion and trapping of hydrogen in high purity aluminum.Acta Mater 46 (1998) 6337-6349.9.JR Scully,GA Young and SW Smith.Hydrogen solubility,diffusion and trapping in high purity aluminum and selected Al-base alloys.Materials Science Forum 331-337 (2000) 1583-1600.10.MR Louthan and G Caskey.Technical Reference on Hydrogen Compatibility of MaterialsThe diffusion and trapping of hydrogen in high purity aluminum.Acta Mater 46 (1998) 6337-6349.16.E Hashimoto and T Kino.Hydrogen diffusion in aluminum at high temperatures.J Phys F Met Phys 13 (1983) 1157-1165.17.C San Marchi,BP Somerday

Previous123456NextDiffusion of Hydrogen and Deuterium in High Purity

with hydrogen was reviewed by Smith in 1948 (1) and by Gulbransen in 1954 (2).Two studies have been made of the kinetics of the reaction with hy- drogen.Gulbransen and Andrew (3) studied the rate of hydriding between 200 ~ and 300~ using high purity metal and a source of highly purified hydrogen.Molecular mechanics and dynamics simulation of hydrogen The main impurities in aluminum melt are hydrogen and Al2O3,which can deteriorate melt quality and materials performance.However,the diffusion process of H atoms in aluminum melt and the interactions among Al atoms,Al2O3 and hydrogen have been studied rarely.Molecular mechanics and dynamics simulations are employed to study the diffusion behaviors of different types of hydrogen,such as Mechanisms of hydrogen embrittlement in steels discussion Jun 12,2017 The diffusion and trapping of hydrogen in high purity#0183;As such,the behaviour may well be very different from even a nominally high-purity hydrogen gas experiment.That is quite intriguing in terms of dimple formation,and in terms of the potential difference in hydrogen-accelerated crack growth,if there is a dissociation reaction that is needed at the high-stress area.

Investigation of adsorption,dissociation,and diffusion

To investigate the H 2 purification mechanism of V membranes,we studied the adsorption,dissociation,and diffusion properties of H in V,an attractive candidate for H 2 separation materials.Our results revealed that the most stable site on the V (1 0 0) surface is the hollow site (HS) for both adsorbed H atoms and molecules.III.13 Hydrogen Permeability and Integrity of Steel WeldsBaseline hydrogen diffusion and permeation measurement in high purity iron was completed.Initial results on hydrogen diffusion and permeation in steels and their welds under high hydrogen pressure (up to 2,000 psi) have been obtained for A106 steel and X52 pipeline steels.The effects of weld microstructure on hydrogen trapping,diffusionIII.13 Hydrogen Permeability and Integrity of Steel WeldsBaseline hydrogen diffusion and permeation measurement in high purity iron was completed.Initial results on hydrogen diffusion and permeation in steels and their welds under high hydrogen pressure (up to 2,000 psi) have been obtained for A106 steel and X52 pipeline steels.The effects of weld microstructure on hydrogen trapping,diffusion

Hydrogen diffusion in aluminium at high temperatures

The activation energy for the diffusion of hydrogen was found to be 0.61-0.62 eV at high temperatures where the concentration of vacancies was much higher than that of dissolved hydrogen.Hydrogen Solubility,Diffusion and Trapping in High Purity Hydrogen Solubility,Diffusion and Trapping in High Purity Aluminum and Selected Al-Base Alloys p.1583 Intergranular Hydrogen Trapping in Al-Mg A Monte Carlo SimulationHydrogen Purification Methods - TechnologyTechnology Considerations on Hydrogen Generation Technology.Hydrogen Generators that are utilised to provide Carrier Gas for GC and GC/MS applications employ many technologies to provide high purity hydrogen.Here were look at the various methods used to purify hydrogen.Three using PEM (Proton Exchange Membrane),combined with various purification techniques,and the fourth using a combined

Hydrogen Purification Methods - Technology Considerations

Technology Considerations on Hydrogen Generation Technology.Hydrogen Generators that are utilised to provide Carrier Gas for GC and GC/MS applications employ many technologies to provide high purity hydrogen.Here were look at the various methods used to purify hydrogen.Three using PEM (Proton Exchange Membrane),combined with various purification techniques,and the fourth using a combined Hydrogen Permeability and Diffusivity in Nickel and Ni Hydrogen diffusion and trapping in metals.Gaseous Hydrogen Embrittlement of Materials in Energy Technologies,89-128. (1990) Electrochemical permeation of hydrogen in high purity nickel at 100 The diffusion and trapping of hydrogen in high purity#176;C.Scripta Metallurgica et Materialia 24:3,499-504.Online publication date 1-Mar-1990.Hydrogen Diffusivity During Corrosion of High-Purity The effective diffusivity of hydrogen in as-annealed (550 The diffusion and trapping of hydrogen in high purity#176;C for 5 h) 99.999% purity polycrystalline aluminum was determined using Al/Pd bilayer membranes following the procedure of K.R.Hebert.Bulk diffusion control was verified by the foil thickness variation method.

Hydrogen Diffusivity During Corrosion of High-Purity

The effective diffusivity of hydrogen in as-annealed (550 The diffusion and trapping of hydrogen in high purity#176;C for 5 h) 99.999% purity polycrystalline aluminum was determined using Al/Pd bilayer membranes following the procedure of K.R.Hebert.Bulk diffusion control was verified by the foil thickness variation method.Hydrogen Diffusivity During Corrosion of High-Purity The effective diffusivity of hydrogen in as-annealed (550 The diffusion and trapping of hydrogen in high purity#176;C for 5 h) 99.999% purity polycrystalline aluminum was determined using Al/Pd bilayer membranes following the procedureHydrogen Compatibility of Materials - Energy.gov4 1) Hydrogen-surface interactions molecular adsorption and dissociation producing atomic hydrogen chemisorbed on the metal surface 2) Bulk metal-hydrogen interactions dissolution of atomic hydrogen into the bulk and segregation to defects in the metal (i.e.,transport and trapping)

Hydrogen Compatibility of Materials - Energy.gov

4 1) Hydrogen-surface interactions molecular adsorption and dissociation producing atomic hydrogen chemisorbed on the metal surface 2) Bulk metal-hydrogen interactions dissolution of atomic hydrogen into the bulk and segregation to defects in the metal (i.e.,transport and trapping)HYDROGEN DIFFUSION AND TRAPPING INHYDROGEN DIFFUSION AND TRAPPING IN ELECTRODEPOSITED NICKEL by THOMAS MILLER HARRIS B.S.,Butler University (1979) determined in high-purity,well-annealed nickel,but approximately equal to that for binding Since the rate of hydrogen diffusion in nickel is relatively slow,the second step is usually theH2 Permeability and Integrity of Steel WeldsBaseline high-pressure hydrogen diffusion and permeation measurement with pure Iron,September 2007 (complete) Baseline study on friction stir welding of pipeline steels,December,2007 (complete) Effect of weld microstructure on hydrogen trapping,diffusion and permeation,June 2008 Initial study on weld mechanical property degradation,

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In the present work,the diffusion of hydrogen in high-purity aluminium was measured using the permeation method,and the findings were compared with calculated results.2.Experimental procedure 2.1.Aluminium specimen The material used in the present experiment was zone-refined aluminium whose purity was 99.9999% (Kino et a1 1976).Diffusivity of hydrogen in pure iron - Bryan - 1963 The rate of permeation of hydrogen through a highly purified iron (Ferrovac E) was measured over a pressure range of 1/30 to 300 atm.and a temperature range of 126 The diffusion and trapping of hydrogen in high purity#176; to 693 The diffusion and trapping of hydrogen in high purity#176;C.The effect of cold working of the annealed metal and of hydrogen purity were also studied.Permeability,diffusivity,and solubility were obtained from the data.Diffusivity of hydrogen in pure iron - Bryan - 1963 The rate of permeation of hydrogen through a highly purified iron (Ferrovac E) was measured over a pressure range of 1/30 to 300 atm.and a temperature range of 126 The diffusion and trapping of hydrogen in high purity#176; to 693 The diffusion and trapping of hydrogen in high purity#176;C.The effect of cold working of the annealed metal and of hydrogen purity were also studied.Permeability,diffusivity,and solubility were obtained from the data.

Diffusion Coefficient of Hydrogen in Iron without Trapping

In order to obtain the diffusion coefficient of hydrogen in iron free from trapping by dislocations and impurities,electrochemical permeation measurements have been done using high purity iron (99.99 mass% Fe),pure iron (99.99 mass% Fe,high substitutional and low interstitial impurity contents),pure iron (99.94 mass% Fe),and commercially pure iron (99.83 mass% Fe) between 278 and 318 K.Diffusion Coefficient of Hydrogen in Iron without Trapping In order to obtain the diffusion coefficient of hydrogen in iron free from trapping by dislocations and impurities,electrochemical permeation measurements have been done using high purity iron (99.99 mass% Fe),pure iron (99.99 mass% Fe,high substitutional and low interstitial impurity contents),pure iron (99.94 mass% Fe),and commercially pure iron (99.83 mass% Fe) between 278 and 318 K.Cited by 251Publish Year 1998Author G.A.Young,J.R.ScullyHydrogen Solubility,Diffusion and Trapping in High Purity Hydrogen Solubility,Diffusion and Trapping in High Purity Aluminum and Selected Al-Base Alloys.May 2000; Diffusion and Trapping in High Purity Aluminum and Selected Al-Base Alloys.

Cited by 24Publish Year 1963Author W.L.Bryan,B.F.DodgeEffective Hydrogen Diffusion in Aluminum Alloy 5083-H131

Recently,bulk diffusion in high-purity Al under corroding conditions was confirmed via the foil thickness variation method.34-35 In this study,a modified D-S method was used to explore the hydrogen diffusion and trapping in AA5083.Abstract Modeling Trapping of Hydrogen Absorbed into In the case of the high purity aluminum-hydrogen system of interest here,hydrogen diffusion and thermal desorption measurements both suggest the importance of trapping by vacancies and dislocations.2 Evidence for strong hydrogen interactions with vacancies in many metals has been obtained both experimentally,3,4 and through first-principles Abstract Modeling Trapping of Hydrogen Absorbed into In the case of the high purity aluminum-hydrogen system of interest here,hydrogen diffusion and thermal desorption measurements both suggest the importance of trapping by vacancies and dislocations.2 Evidence for strong hydrogen interactions with vacancies in many metals has been obtained both experimentally,3,4 and through first-principles

About the Role of Hydrogen in Stress Corrosion Cracking of

The effects of hydrogen during stress corrosion cracking mechanisms (SCC) have been highlighted for many years but hydrogen trapping mechanisms are not yet well understood for 7xxx aluminium alloys.The 7046-T4 Al-Zn-Mg alloy has been chosen for this study because its low corrosion susceptibility allows hydrogen embrittlement (HE) to be more easily distinguished during SCC tests.12345NextDiffusivity of hydrogen in pure iron - Bryan - 1963 The rate of permeation of hydrogen through a highly purified iron (Ferrovac E) was measured over a pressure range of 1/30 to 300 atm.and a temperature range of 126 The diffusion and trapping of hydrogen in high purity#176; to 693 The diffusion and trapping of hydrogen in high purity#176;C.The effect of cold working of the annealed metal and of hydrogen purity were also studied.Permeability,diffusivity,and solubility were obtained from the data.(PDF) Trapping against hydrogen embrittlementThe effect of predissolved H concentration on the fracture resistance,K IH ,of H 2 precharged compact tension specimens of modern (high purity) 2 The diffusion and trapping of hydrogen in high purity#188;Cr-1Mo steel stressed in moist air at 23-25 The diffusion and trapping of hydrogen in high purity#186;C.

(PDF) Trapping against hydrogen embrittlement

The effect of predissolved H concentration on the fracture resistance,K IH ,of H 2 precharged compact tension specimens of modern (high purity) 2 The diffusion and trapping of hydrogen in high purity#188;Cr-1Mo steel stressed in moist air at 23-25 The diffusion and trapping of hydrogen in high purity#186;C.(PDF) Hydrogen trapping in heat treated and deformedHydrogen trapping in the Fe0.01 mass% C was significantly increased by HPT processing,because of high binding energies of hydrogen with lattice defects such as dislocations and grain